理學部化學科

研究室紹介 有機金屬錯體研究室

教員仲谷 學(助教)博士(理學)
略歴2013年3月
2015年3月
2018年3月
2015年4月-2018年3月
2018年4月-2020年3月
2018年4月-2020年3月
2020年4月-
2020年5月-
熊本大學理學部理學科化學コース 卒業
熊本大學大學院自然科學研究科理學専攻(化學系)博士前期課程 修了
熊本大學大學院自然科學研究科理學専攻(化學系)博士後期課程 修了
日本學術振興會 特別研究員(DC1)
東京大學大學院理學系研究科 特別研究員(塩谷光彥研究室)
日本學術振興會 特別研究員(PD)
城西大學理學部化學科 助教
東京大學大學院理學系研究科 客員共同研究員(塩谷光彥研究室)
擔當科目化學基礎セミナーII、有機化學実験、有機化學IIB、化學ゼミナール?コロキウム、卒業研究
専門分野構造有機化學、錯體化學、超分子化學、生物無機化學
所屬學會日本化學會、錯體化學會、錯體化學若手の會、生體機能関連化學部會
院生0名
4年生2名
居室1號館202號室
メールアドレスnakaya

研究內容

本研究室では、金屬錯體の集積構造制御とそれに伴う物性(磁気特性、発光特性、伝導性など)の制御を目指しています。分子設計性が多様な単核錯體に著目し、狙ったとおりの分子集積を可能にする有機配位子の合成および種々の金屬イオンを用いた金屬錯體合成を行います。錯體の結晶化や、固體狀態での物性測定、さらには溶液中での新奇物性発現も目指しています。

昨年度の卒業研究題目

新設研究室につき無し

最近の研究業績

  1. “CO2-induced spin state switching at room temperature in a monomeric cobalt(II) complex with the porous nature”
    Manabu Nakaya, Wataru Kosaka, Hitoshi Miyasaka, Yuki Komatsumaru, Shogo Kawaguchi, Kunihisa Sugimoto, Yingjie Zhang, Masaaki Nakamura, Leonard F. Lindoy, Shinya Hayami
    Angew. Chem. Int. Ed., 2020, In press.
  2. “Abrupt spin transition in a modified-terpyridine cobalt(II) complex with a highly-distorted [CoN6] core”
    Manabu Nakaya, Ryo Ohtani, Jong Won Shin, Masaaki Nakamura, Leonard F. Lindoy, Shinya Hayami
    Dalton Trans., 2018, 47, 13809-13814. (Inside back Cover)
  3. “Post-synthetic modification of a dinuclear spin crossover iron(III) complex”
    Yuki Komatsumaru, Manabu Nakaya, Fumiya Kobayashi, Ryo Ohtani, Masaaki Nakamura, Leonard F. Lindoy, Shinya Hayami
    Z. Anorg. Allg. Chem., 2018, 644, 729-734.
  4. “Intermolecular Interaction Tuning of Spin-Crossover Iron(III) Complexes with Aromatic Counteranions”
    Asami Tsukiashi, Manabu Nakaya, Fumiya Kobayashi, Ryo Ohtani, Masaaki Nakamura, Jack M. Harrowfield, Yang Kim, Shinya Hayami
    Inorg. Chem., 2018, 57, 2834-2842.
  5. “Supramolecular architectures self-assembled using long chain alkylated spin crossover cobalt(II) compounds”
    Ryohei Akiyoshi, Keita Kuroiwa, Saliu Alao Amolegbe, Manabu Nakaya, Ryo Ohtani, Masaaki Nakamura, Leonard F. Lindoy, Shinya Hayami
    Chem. Commun., 2017, 53, 4685-4687. (Inside back cover)
  6. “Molecular Assemblies of Metal Complexes via Base Pairing of Nucleic Acids in the Crystalline State”
    Manabu Nakaya, Ryo Ohtani, Kunihisa Sugimoto, Masaaki Nakamura, Leonard F. Lindoy, Shinya Hayami
    Chem. Eur. J., 2017, 23, 7232-7237. (Hot paper, Frontispiece)
  7. “Molecular Assemblies and Spin-Crossover Behaviour of Cobalt(II) Complexes with Terpyridine Incorporating Different Nitrogen Positions in Pyridine Rings”
    Risa Nakahara, Manabu Nakaya, Jong Won Shin, Ryo Ohtani, Masaaki Nakamura, Shinya Hayami
    Aust. J. Chem., 2017, 70, 494-498.
  8. “Water-dependent charge-transfer-induced spin transition of Prussian blue analogues”
    Hitomi Ohmagari, Ryo Ohtani, Manabu Nakaya, Masaaki Ohba, Masaaki Nakamura, Leonard F. Lindoy, Osamu Sato, Shinya Hayami
    Dalton Trans., 2016, 45, 16784-16788.
  9. “Metal Dilution Effects on the Reverse Spin Transition in Mixed-Crystals of Type [Co1-xZnx(C16-terpy)2](BF4)2 (x=0.1-0.7)”
    Ryo Ohtani, Saki Egawa, Manabu Nakaya, Hitomi Ohmagari, Masaaki Nakamura, Leonard F. Lindoy, Shinya Hayami
    Inorg. Chem., 2016, 55, 3332-3337.
  10. “Molecular Designs for Enhancement of Polarity in Ferroelectric Soft Materials”
    Ryo Ohtani, Manabu Nakaya, Hitomi Ohmagari, Masaaki Nakamura, Kazuchika Ohta, Leonard F. Lindoy, Shinya Hayami
    Sci. Rep., 2015, 16606 published online.
  11. “Crystal structure of bis[4'-(1,4,7,10-tetraoxa-13-azacyclopentadecan-13-yl)-2,2':6',2''-terpyridine] cobalt(III) tris(perchlorate) methanol monosolvate monohydrate”
    Hitomi Ohmagari, Manabu Nakaya, Ryo Ohtani, Masaaki Nakamura, Shinya Hayami
    Act. Crys., E, 2015, 71(8), 997-999.
  12. “Direct Observation of Low-Temperature Bistability in an Iron(III) LIESST Compound”
    Naoto Saigo, Yusuke Sekimoto, Manabu Nakaya, Ryo Ohtani, Masaaki Nakamura, Shinya Hayami
    J. Incl. Phenom. Macrocycl. Chem., 2015, 82, 225-228.
  13. “Photoswitching of the Dielectric Property of Salicylideneaniline”
    Kodai Shimayama, Mohammad Razaul Karim, Saliu Alao Amolegbe, Manabu Nakaya, Masaaki Nakamura, Ryo Ohtani, Leonard F. Lindoy, Shinya Hayami
    J. Incl. Phenom. Macrocycl. Chem., 2015, 82, 219-223.
  14. “Crystal Structures and Magnetic Properties of Manganese(III) Complexes with Tridentate Schiff Base Ligands”
    Hitomi Ohmagari, Aya Fukahori, Manabu Nakaya, Ryo Ohtani, Masaaki Nakamura, Shinya Hayami
    J. Incl. Phenom. Macrocycl. Chem., 2015, 82, 213-218.
  15. “Spin-crossover behaviors in solvated cobalt(II) compounds”
    Shinya Hayami, Manabu Nakaya, Hitomi Ohmagari, Amolegbe Saliu Alao, Masaaki Nakamura, Ryo Ohtani, Ryotaro Yamaguchi, Takayoshi Kuroda-Sowa, Jack K. Clegg
    Dalton Trans., 2015, 44, 9345-9348. (Inside back cover)
  16. “Spin-crossover and LIESST Effect for Iron(III) Complex Based on π-π Stacking by Coordination Programing”
    Manabu Nakaya, Kodai Shimayama, Kohei Takami, Kazuya Hirata, Amolegbe Saliu Alao, Masaaki Nakamura, Leonard F. Lindoy, Shinya Hayami
    Chem. Lett., 2014, 43, 1058-1060.
  17. “Structures and Magnetic Properties of Iron(III) Complexes with Long Alkyl Chains”
    Manabu Nakaya, Kodai Shimayama, Kohei Takami, Kazuya Hirata, Saliu Alao Amolegbe, Masaaki Nakamura, Leonard F. Lindoy, Shinya Hayami
    Crystals, 2014, 4, 104-112.
  18. “Crystal structure and Spin-crossover Behavior of Iron(III) Complex with Nitroprusside”
    Takahiro Togo, Saliu Alao Amolegbe, Ryotaro Yamaguchi, Takayoshi Kuroda-Sowa, Manabu Nakaya, Kodai Shimayama, Masaaki Nakamura, Shinya Hayami
    Chem. Lett., 2013, 42, 1542-1544.
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